Capsaicin
Capsaicin is the most common chemical compound associated to the heat from a chile. Capsaicin belongs to a family of chemicals called capsaicinoids which are produces by chiles. Capsaicinoids bind to nerve receptors on the tongue or back of the throat, and they allow the flow of calcium into the cell causing a pain signal to be transmitted (or so I'm told).
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In 1912, Wilbur Scoville developed a subjective method of ranking chiles. Scoville mixed ground chile in a simple syrup (sugar and water solution) and had a panel of tasters taste the solutions. The ratio of simple syrup to chile where the tasters were unable to taste the chile spiciness was the rating given to the chile. For example, a serrano chile might need 8000 parts simple syrup to 1 part chile before you would be unable to taste the chile.
As you can imagine, this system seems a bit too subjective. Everyone has different tolerances for tasting spicy foods, the panelists may have grown up eating chiles and become desensitized, and the process of tasting chiles probably helps desensitize the taste buds. The solution? High-Performance Liquid Chromatography.
High-Performance Liquid Chromatography (HPLC)
Becoming popular 1970's, HPLC is a method of separating compounds within a solution under high pressure. Once the solution has been separated, the parts can be identified and quantified. Applying HPLC can be used on ground peppers, chemists can determine the capsaicinoid concentration in parts per million. The capsaicin concentrating in parts per million is directly proportional to the Scoville rating system - by a factor of approximately 16. Thus, a capsaicinoid level of 200 parts per million results in a Scoville rating of 3200. Pure capsaicin would then have a Scoville rating of 16 million. The downside of HPLC is that it is quite expensive compared to having a bunch of people tasting chile flavored Frutopia...
One of the problems with scoville ratings is that no two sources seem to agree just how hot a chile is. Here's some of the examples that I've managed to collect to provide an idea of how the varieties stack up against each other.
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You obviously haven't had spicy food that's spicy enough!
One drop is enough for my chili con carne.
While there I bought some of their peppers, which added a nice touch to my dad's homemade picante salsa. Had to get a Tabasco tie also =)
I'm Mexican (raised in Mexico) and don't eat chilies, what a joke eh?! Never heard of this scale for measuring hotness. All I know is, my cousins from Puebla cannot live without habaneros, they eat them by the handful, raw, by themselves... geez! I think it's funny some people write habañeros... no tilde needed on the N people!! Haha.
I love your page, I'm a frustrated engineer, and cook!
Here in Australia, 'bell peppers' are called Capsicums. Until reading your article I never knew the reason - I am assuming now it has something to do with the name of this chemical Capsaicin.
It led to a lot of confusion and intrigue when I visited Subway in the States. ("You want *what* on your sandwich?!")
Capsicum is the genus of all chiles from bell peppers to habaneros. The name of the chemical capsaicin comes from the name for chile - capsicum.
The day after I set up a blog for my new job at peppertalk.salsaexpress.com with you in the links even!
Having grown up on hot food – our school cafateria had pickle jars of all-you-can-eat jalapenos on the tables – I am what some people may consider (judging from previous comments) either masochistic or insane. So now I work for a "Fiery Foods" company as part of an absolutely crazy and fun industry!
I too love to eat habaneros raw. They have a definite kick but they also have a fruity flavor to them. That fruitiness makes them excellent peppers for use in desserts, fruit salsas and other fruit (especially citrus) recipes. Thai's though are all attitude. Not quite as hot, but no fruitiness. Every pepper has it's own unique flavor, and even substrains have very distinctive flavors as well as heat levels. Some build in heat as you eat more of them, some stay at the same level.
Dave's Ultimate Insanity, has a couple challengers to the title of th hottest hot sauce now... there's Dave's own challenger to the title "Dave's Ultimate Insanity Limited Reserve" label, and there's "Endorphin Rush" (you can find them at Salsa Express among other places.)
Whatever you do don't use these sauces like you might use Tobasco. I made that mistake once. Thought I grabbed the tobasco and put a good 5-6 shakes into a tomato soup. Wow! It took a half gallon of milk and a pint of ice cream to get my mouth back to near normal. And remember I do eat hab's raw!
I always wondered about the Australian way of refering to peppers. Capsicum is the genus name of the nightshade family of plants that includes both Bell Peppers (C. annuum) and the habanero (C. chinense) so it definitely makes sense...just different.
Did you know that birds can't taste hot peppers?
Apparently, a lot of the peppers rely on birds for seed dispersal. The hot flavor discourages mammals from eating them, but not birds.
EVEN MORE TRIVIA
Did you know that vampire bats have no sense of taste?
They drink blood, and there isn't much useful information one can get from the taste of blood. Blood from a living animal is never toxic.
I wonder if it's possible that the smoking process removes some of the water content - so that more parts are included in the HPLC test. (at least I think that's what I understood about the process) Sort of the same way that fresh herbs are not as intensely flavoured as the same quantity of dried herbs.
I'm surprised that "piri-piri" or "African birdseye" chilis - the ones that look like tiny Thai chilis - are missing from that list. Some people argue that the piri-piri is the hottest. (Of course, I cannot find anything on the net that corroborates this....)
Two summers ago, we did some taste tests of various Salsas made from dried chilies that may be of interest to any of you chiliheads.
When I was little, my grandmother used to put one whole in several gallons of soup then let me stir with a strong warning to not break the pepper because the soup would be too hot to eat. I "experimented" and proved her very right.
This also is a good reason why it's a good idea to combine different "heats" (tabasco, habanero, cayenne, plus black AND white pepper) in a recipe. Paul Prud'homme explains this principle in his cookbooks (gumbo recipes).
Trust me I know I was a List member on the now it seems defunct Chileheads List for 10 years..
I currently am growing Houston USA sourced Tepins here in OZ (why because the little shits are hard to grow, and I take it as a Personal Challenge".. FWIW i won 2 out of three local Chile Eating contests here, first time was 1 15 oz glass of blended chiles Habanero's included second time was 12 Habaneros , third time as defending champ i was nobbled by being made to take a small tub of Extract based sauced probably 350k scovies before participating and even then the guy who beat me swallowed several Habaneros whole.. "we were supposed to chew them for the ammusement of the 2000+ crowd..
FWIW Blairs Death sauce brand has more flavour than Daves, Std disclaimers apply although I did have snail mail intercourse with Blair Lazar once in 95-96..
A Fireman mate of mine Jim Campbell in Franklin Indiana does a mean apple smoked habanero Flake and lots of other products, no disclaimer apply here as he does send me a care package of new products from time to time
Luke in OZ
{Just testing to see if the admin forgot to turn off the priveleges for 'other' people to edit 'guest' posts. If so, then the admin will need to turn off this feature. - Kenny}
{update....yes...this is no good, I will have to inform the admin to fix this up...it means others can change this message too. Not good.}
For a more reliable but not as cool source, try a chemical supply company that will gladly sell you a gram of synthetic capsaicin for around $650 (natural will run you $950): Fisher Scientific
Finally, here's a list of manufacturers of pure capsaicin:
Buyers Guide Chem
(exampe: take xxx grams of peppers, keep in xxx ml of alcohol, etc>).
many thanks.
- Kenny
Thus the chipotle pepper (being ripe) is hotter than the green jalapeno. Drying the pepper serves to increase the heat as a ratio of mass, but scoville units are a measure of capsaicin capacity, not ration so drying the pepper does not change the scoville rating.
Do you have references for the 16 figure? Most other sources speak of a factor of 15, which would also put the max attainable SCU value at 15 million.
We have a type of pepper that grows down here on the isthmus of Panama commonly called a pico de pajaro, but if that term is used as a search term a completely different type of pepper is what comes up on google.
What we call pico de pajaro here in panama is a very small, roundish pepper which grows wild and is very hot.
Just something interesting I came across.
The lemonade is served cold but is heated up to a minimum of 90,000 Scolville and is used to boost energy and a number of other benefits. Check out both.
If you like them, don't forget to digg them by clicking the little dig icon.
http://digg.com/science/digg/page2
A regular Habanero hot sauce averages about 20,000 to 30,000 Scoville units. The "extract" sauces (usually named stuff like Devils Drool, or Blair's Mega Death, and have entertaining packaging) contain much higher concentrations of Capsaicin extract and range from 250,000 to 550,000 Scoville units. Needless to say that is extremely hot. So much so they carry warnings that they are to be dilluted and used on a per drop basis, and should be kept in a safe place. Generally 300,000 to 550,000 Scoville unit sauces are the apex of heat for even the seasoned "chileheads", and will undoubtedly induce a lot of sweating, eye tearing and nasal drip for a good 10 minutes or so in small applications. The Black Mamba however is in a group of maybe four or five in the world that carry the highest concentraions of Capsaicin at inordinately high levels. Black Mamba was tested and shown to have several million Scoville units per bottle! What this means is a toothpick sized droplet will burn burn burn in a way that nothing ever has before. I now know this to be true. I tasted a drop on a tortilla chip this morning and in the first few minutes almost wished I hadn't. My pallete was aflame with something I didn't perceive to be edible. My throat felt like something had literally blazed a trail through it, my sinuses were vaporized by what I liken to inhaling ammonia to keep from passing out, my entire head was sweating like I had just run 10 miles, and my eyes were a watery mess. This all from a single drop of this stuff (no lie). I seriously couldnt take the heat, and I admittedly enjoy hot foods, so that should gibve you a good indication at the power of this stuff. There is another sauce called The Source which is measured at 7 million Scoville units which is obviously ridiculous.
The Blair's private reserve collection has the Guinness record in Scoville measured heat with his 16million Reserve pure Cap flake. It's not even extract which is already uber hot, it's actually pure Capscium flake which is like oleoresin heat at extreme concentrations. You need to sign a waiver to even purchase the stuf,f and it has to be handled with gloves and safety glasses (not a joke - seriously). Reportedly one couple of seasoned chiliheads dropped a flake into a pot of soup, melted and stirred it in and both couldn't handle the heat. Another guy at a radio station tried it on the air and was sent to the hospital with respiratory problems.
If you're interested in genuine heat that won't kill you, your best bet is a max of 550,000 scoville to the most at maybe a million. Try something like Blair's Mega Death which is a nice 550,000 Scoville and you'll get what you're looking for.
There are a wide varity of products out there, many of us collect them.
The must visit links for serious chiliheads:
www.hotsauceworld.com
www.hotsauceblog.com
-
~TC~
www.firegirl.com
They are very informative and sell a wide variety of sauces from mild to deadly.
Also, ER is low sodium.
Also try this for 16 Million:
http://www.hotsauceblog.com/hotsaucearchives/blairs-16-million-product-review/
and
http://www.sweatnspice.com/429-13.htm
Good luck and eat safely.
<...snip...>
Good luck and eat safely.
ER's 33.390K is more than hot enough for this old fool and it helps me watch my sodium ;-)
I like an endorphin buzz, but I don't want to wake up in the ER (the other acronym).
This didn't show up in my usual Opera, so I tried it in Firefox, Lynx, and then (with much trepidation) fired up Internet Exploder (7). No dice, no table, no lucky streak...
This also is a good reason why it's a good idea to combine different "heats" (tabasco, habanero, cayenne, plus black AND white pepper) in a recipe. Paul Prud'homme explains this principle in his cookbooks (gumbo recipes).
AFAIK, there is only one type of receptor (called VR1) which 'detects' capsaicinoids (the group as a whole) some have more effect (cause more/less pain). Therefore to say different capsaicinoids affect different parts of the mouth/throat is erroneous, and therefore using different chillies would not give any difference in pain location. Just another urban myth, I'm afraid.
There are only four main tastes: salt, sweet, bitter, sour. If you count unami, the flavor of MSG, there are five. However, not everybody can taste unami, which explains why some people can tell you on the first bite when they eat food that has MSG. Most all "flavors" are actually smelled, so don't expect a gourmet creation from a cook who has a cold or summer allergies.
But, besides hot, there is absolutely wonderful flavor in one of the hot peppers, the habanero. This sauce is fantastic in stew, soup, or many foods where more depth of flavor is desirable. Doubt me....just try in a small, safe quantity. And, yes, you are welcome....in advance.
Little did I understand why, until about 5 minutes later, ... Yes I'll admit, it was Hot on the lips as an after-taste , spicy on the tongue, But little did i know what would happen when it finally hit my stomach ! ... I wont tell you the result of downing this 1/2 shot of The Bomb ( too graphic - and I
would rather you find out yourselves ) ...but I will tell you this.... It's Scoville Unit measurement was exactly 855,000 scoville units ... yes, you heard me...not a typo....855,000 scoville units ... now having just read this...I'll also tell you that it's NOT the hottest sauce they sell.... I don't know the name of this one, and you have to sign a waiver before purchasing it...but I'll warn you...the deem it "The HOTTEST sauce on earth" ...with a Scoville Unit measurment of an unbelievable 7,000,000 !!
Or...7 million scoville units for those who cant add zeroes....anyone "man" enough to try it ? ....I doubt it !!
Little did I understand why, until about 5 minutes later, ... Yes I'll admit, it was Hot on the lips as an after-taste , spicy on the tongue, But little did i know what would happen when it finally hit my stomach ! ... I wont tell you the result of downing this 1/2 shot of The Bomb ( too graphic - and I
would rather you find out yourselves ) ...but I will tell you this.... It's Scoville Unit measurement was exactly 855,000 scoville units ... yes, you heard me...not a typo....855,000 scoville units ... now having just read this...I'll also tell you that it's NOT the hottest sauce they sell.... I don't know the name of this one, and you have to sign a waiver before purchasing it...but I'll warn you...the deem it "The HOTTEST sauce on earth" ...with a Scoville Unit measurment of an unbelievable 7,000,000 !!
Or...7 million scoville units for those who cant add zeroes....anyone "man" enough to try it ? ....I doubt it !!
Check this out:
http://www.hotsauceworld.com/bl6amrepeexe.html
This is up to 16 Million scoville units.
I remember being at a bar about ten years ago where they were featuring various brands of Tequila shots and serving gratis Buffalo wings. One of the patrons was being a loud pain in the butt, repeatedly saying the wings weren't hot enough in a really annoying manner. He said there wasn't a hot sauce that he couldn't eat. The bartender, having had enough of the guy, gave him a spoon and a bottle of Dave's Ultimate Insanity, and then walked away. The annoying patron apparently never heard of it because he poured a spoonful and downed it like it was cough medicine. He had a reaction just like you described. He had too big an ego to admit he was dying. He excused himself to the men's room, and didn't return.
I'm surprised that the restaurant you went to served the Da Bomb as a condiment, instead of using it as a "food additive" that it is really meant to be. The ultra high octane hot sauces can be dangerous to a person's health.
when purchasing this hot sauce at a local vendor i had to sign a waiver to not use the sauce in practical jokes. it wasnt cheap but its been worth every penny. they do have other sauces in the million ratings of which i am looking forward to tasting, after some serious training. a little bit of Ye Olde Colon Cleanser. yee haa!! seriously, i love their sauces as they are not loaded with sodium. and i guess that some people just can handle heat. years ago i went on a trip to Cancun Mexico for Christmas with a couple friends. we ended up taking a snorkeling tour around the islands. part of the tour involved having a meal prepared on a small private island. i asked our waiter if they could make a Habanero sauce for me to go along with the copius amount of grilled meat. they brought out a nice zesty sauce for me. it was a perfect match for the meal. my friends saw me eating with such gusto that they decided to try the sauce. just a dip of the fork into the sauce to check for heat. they didn't think it was that hot as they saw me pouring it over my food. needles to say the sauce proved more than a match for them. it ruined the rest of their meal. and i had a good laugh at their expense. some people just cant handle any heat i guess.
http://www.nmsu.edu/~ucomm/Releases/2007/february/hottest_chile.htm
If your sauce has any preservatives in the ingredients list, you can forget about it. A good hot sauce does not need them, as they are anti-fungal, anti-bacterial. In fact the compounds in there are made by nature to prevent you from eating them. Oh, well so much for the evolutionary reasoning.
And on the side -- having Blairs Megadeath around for a while (actually much longer than any of the others) I noticed that the heat is painful, but shallow. I prefer to add more of a rich, flavourful sauce as my long term favourite, called Alberta Crude. By far not as hot (would guess in the 5-15% range of megadeath) but, hey, add more AND you get the depth with the heat.
Cheers!
Ricante Hot Sauce & Cevicheria has a line of hot sauces that aim not only to provide an enjoyable burning sensation but also to add flavor and spice to your meals. Our hot sauces bring the tropical flavors of Costa Rica (well, CR's food is not really flavorful but the country is) combined with the spiciness of Mexican food.
You can buy Ricante hot sauce online, or come enjoy a refreshing bowl of ceviche if you are in the Tamarindo area. We can also do custom labels which makes for a great gift, what better than to hot sauce as a gift[/url]!
Pura vida![/url]
hot peppers, hot sauce, or even extract , or capsaicin will NOT kill taste buds.